On a quest to understand humanity, Bai Suzhen starts off by challenging the expertise of physician Xu Xian but finds a rival named Qing ready for her.

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After Bai ponders an intervention to heal a strangely sick mother, a noble decision by Xu captures her attention.

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Chaos erupts at the Lantern Festival, forcing Bai to defy the heavens. Meanwhile, fighting monk Fahai finds out why the city's children are missing.

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With an assist from an old friend named Jingsong, Bai attempts to find the missing children and learns the truth about the powerful culprit.

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Bai fights the powerful culprit with a crew of former adversaries and later tests Xu's integrity when she gets suspicious of the people around him.

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At Xu's family dinner, Bai must act as a mere mortal but faces friction from his longtime admirer, Jin Ruyi.

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While Officer Li Gongfu faces roadblocks in a murder investigation, Jingsong urges Bai to make a life-changing decision for her own well-being.

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Xu challenges Bai's decision with a declaration, prompting foxy responses from Ruyi and a new enemy known as Hu Kexin.

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Suspicious of Xu's shocking behavior, Jingsong and Qing take action, which leads to a swift response from Bai and a fatal result.

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When Bai finds herself caught in a public trial, Xu makes a desperate push to proclaim her innocence.

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Jingsong gives Kexin an ultimatum. Bai finally learns the motives behind the murder that shook up Xu's life and the entire city.

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When Xu becomes mysteriously ill after the city averts disaster, Bai seeks an antidote that will require tremendous sacrifice.

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Bai's major sacrifice forges a new path with Xu but leads to suspicion and displeasure from Officer Li, Ruyi and Jingsong.

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After Bai and Xu make their new path official, she discovers a secret regarding his finances and wonders how to respond.

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Bai and Xu start an emerging venture that draws an unscrupulous response from Prime Minister Liang, threatening their lives.

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As a hunter named Zhang Yutang occupies Qing's mind, Xu and Bai investigate the murky nature of a plague that profits Ruyi's clinic.

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Wang Daoling, Ruyi's new physician, must reveal his real identity when Xu and Bai's investigation into the new plague breaks wide open.

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When Daoling finally discloses Bai's hidden identity to Ruyi, she plots to keep Xu away from Bai with the assistance of an unaware Fahai.

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Ruyi's plan unexpectedly puts Xu's life in jeopardy, pushing Bai to rescue him by searching for a solution in a prohibited land.

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Bai finds trouble in the prohibited land and makes a dire plea, but granting this request will change her and Xu's lives forever.

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As Xu struggles with his new way of life, Bai makes a firm decision to alleviate his suffering at the expense of her own pain.

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Everyone moves forward from Bai's decision except for Xu, who makes a startling revelation that rocks Ruyi to the core.

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Xu indulgently dotes on Bai with uncharacteristic behavior, leading her to search for the true reason behind his actions.

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Yutang considers an offer to get closer to Qing while Ruyi conspires with Daoling to dispose of Bai using someone from her inner circle.

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After an unwanted beggar gives Bai and Xu a surprise for treating him, Qing tries to reveal Ruyi's secret but gets unexpected news about herself.

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With growing concerns about Qing's relationship with Yutang, Bai makes an appeal to the immortal Dragon King.

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Qing searches for a way to solidify her situation with Yutang, but Fahai's battle with the Mind Demon and Bai's fate could thwart her quest.

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While Bai and Xu assist Fahai in his fight against the Mind Demon, Qing must decide if she will forever alter her relationship with Yutang to save him.

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Daoling conspires to pit Xu against his close friend while the Mind Demon possesses the body of someone in Xu's inner circle.

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After Bai helps Xu understand his past so he can expose Prime Minister Liang, Xu's sister Jiaorong gets good news that Bai knows is secretly tainted.

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Certain of Bai's intentions, Xu makes a bold decision that he hopes will preserve the future of his sister Jiarong and her family.

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Misunderstandings and powerful truths are revealed when an attempt to save Jiaorong leaves everyone else reeling, especially Bai.

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Xu undergoes a dangerous experiment to reverse a tragedy while Qing's vengeful spirit requires a major intervention.

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As the truth about the spiritual world spreads through the city, the question of mortality faces Bai and Ruyi with new lives at stake for each of them.

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Xu and Fahai consider the only option to stop the Mind Demon from destroying the city, but it requires the ultimate sacrifice -- and hiding it from Bai.

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A final effort to stop the Mind Demon requires an intervention that forces heaven and earth to collide, bringing lasting rewards and punishments.

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